Tris(2,2'-bipyridine-κ2N,N')copper (II) bis-(tetrafluoridoborate)

Chamayou, A. C. ; Biswas, C. ; Janiak, C. ; Ghosh, A. (2007) Tris(2,2'-bipyridine-κ2N,N')copper (II) bis-(tetrafluoridoborate) Acta Crystallographica Section E, 63 (7). m1936-m1937. ISSN 1600-5368

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The title compound, [Cu(C10H8N2)3](BF4)2, shows the expected Jahn-Teller distortion at the pseudo-octa¬hedrally coordinated CuII atom. Each CuII complex cation is surrounded by six BF4- anions and each anion by three cations with weak C-H F hydrogen bonds between them. One of the two BF4- anions exhibits a rotational disorder (0.6:0.4) around one of the B-F bonds.

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ID Code:108378
Deposited On:13 Oct 2017 12:57
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