Maity, Debdulal ; Mukherjee, Pampa ; Ghosh, Ashutosh ; Drew, Michael G. B. ; Mukhopadhyay, Gurucharan (2008) A novel trinuclear nickel (II) complex of an unsymmetrical tetradentate ligand involving bridging oxime and acetylacetone functions Inorganica Chimica Acta, 361 (5). pp. 1515-1519. ISSN 0020-1693
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.ica.2007.08.014
Abstract
A novel trinuclear nickel (II) complex, [Ni3(L)2(H2O)2](ClO4)2, where L is a bridging unsymmetrical tetradentate ligand, involving o-phenylenediamine, diacetyl monoxime and acetylacetone (H2L = 4-[2-(3-hydroxy-1-methyl-but-2-enylideneamino)-phenylimino]-pentan-2-one oxime) has been synthesized and characterized structurally. In the complex, an octahedral Ni(II) centre is held in the middle by two square planar units with the aid of oxime and ketonic bridges.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Trinuclear Ni(II); Unsymmetrical Ligand; Oxime Bridge; Ketonic Bridge; Crystal Structure |
| ID Code: | 108367 |
| Deposited On: | 13 Oct 2017 13:08 |
| Last Modified: | 13 Oct 2017 13:08 |
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