Sarkar, Biswarup ; Bocelli, Gabriele ; Cantoni, Andrea ; Ghosh, Ashutosh (2008) Copper (II) complexes with singly condensed tridentate Schiff-base ligands incorporating 1-benzoylacetone Journal of Coordination Chemistry, 61 (22). pp. 3693-3702. ISSN 0095-8972
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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0095897...
Related URL: http://dx.doi.org/10.1080/00958970802216685
Abstract
Two copper (II) complexes [CuL1Cl]n (1) and [CuL2Cl] (2) with singly condensed tridentate Schiff-base ligands [HL1 = 6-amino-3-methyl-1-phenyl-4-azahex-3-en-1-one and HL2 = 6-diethylamino-3-methyl-1-phenyl-4-azahex-3-en-1-one] have been synthesized and structurally characterized by X-ray crystallography. Complex 1 is a single-chloro-bridged one-dimensional polymer, whereas 2 is a monomeric square-planar complex. The H-bonding interactions of the amine hydrogen and the non-bonding interactions of phenyl groups in the Schiff base play important roles for the structural variations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| Keywords: | Copper (II); Schiff Base; 1-Benzoylacetone; Crystal Structure; Electrochemical Behavior |
| ID Code: | 108358 |
| Deposited On: | 17 Oct 2017 13:01 |
| Last Modified: | 17 Oct 2017 13:01 |
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