Hazra, Shantanu ; Sarkar, Biswarup ; Naiya, Subrata ; Drew, Michael G. B. ; Ribas, Joan ; Diaz, Carmen ; Ghosh, Ashutosh (2011) A self-assembled non-interpenetrating cubic diamondoid coordination polymer of hexamine with linear dicopper spacer: structural and magnetic studies Inorganic Chemistry Communications, 14 (12). pp. 1860-1863. ISSN 1387-7003
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2011.08.024
Abstract
Structural characterization of a new self assembled coordination polymer of CuII, hexamine (hmt) and benzoate (OBz), [Cu4(OBz)8(hmt)]n (1), reveals that it is a cubic non-interpenetrating diamondoid network formed by the coordination of the μ4-hmt ligand to a linear [Cu2(OBz)4] spacer. The magnetic study reveals that the Cu (II) ions are antiferromagnetically coupled (J = − 323.5 cm−1) through the syn–syn carboxylate bridges.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Copper (II); Benzoate; Hexamine; Crystal Structure; Magnetic Properties |
| ID Code: | 108309 |
| Deposited On: | 17 Oct 2017 12:58 |
| Last Modified: | 17 Oct 2017 12:58 |
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