An unusual axial–axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters

Naiya, Subrata ; Biswas, Saptarshi ; Drew, Michael G. B. ; Ghosh, Ashutosh (2012) An unusual axial–axial combination of alternating cyclic rings in the chair conformations of hexameric water and chlorine-water clusters Inorganic Chemistry Communications, 20 . pp. 286-289. ISSN 1387-7003

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.inoche.2012.03.030

Abstract

An alternating hexameric water (H2O)6 cluster and a chlorine-water cluster [Cl2 (H2O)4]2- in the chair forms combine axially to each other to form a 1D chain [{Cl2 (H2O)6}2−]n in complex [FeL2]Cl•(H2O)3 (L = 2-[(2-methylaminoethylimino)-methyl]-phenol)]. The water molecules display extensive H-bonding interactions with monomeric iron–organic units to form a hydrogen-bonded 2D supramolecular assembly.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Hydrogen-bonded; Chlorine-water Cluster; Chair Conformation; X-ray Diffraction Analysis; Decahydronaphthalene
ID Code:108294
Deposited On:17 Oct 2017 13:00
Last Modified:17 Oct 2017 13:00

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