Oxidative properties of a nonheme Ni(II)(O2) complex: reactivity patterns for C–H activation, aromatic hydroxylation and heteroatom oxidation

Latifi, Reza ; Tahsini, Laleh ; Kumar, Devesh ; Sastry, G. Narahari ; Nam, Wonwoo ; de Visser, Sam P. (2011) Oxidative properties of a nonheme Ni(II)(O2) complex: reactivity patterns for C–H activation, aromatic hydroxylation and heteroatom oxidation Chemical Communications, 47 (38). pp. 10674-10676. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2011...

Related URL: http://dx.doi.org/10.1039/c1cc13993b

Abstract

Density functional theory calculations on the reactivity of a Ni(II)-superoxo complex in C–H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(II)-superoxo complex is able to react with substrates with weak C–H bonds and PPh3.

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