Oxidative aromatic C-H functionalization promoted by phenyliodine(III) diacetate to form C-N, C-S, and C-Se bonds

Kumar, Rapolu Kiran ; Manna, Sudeshna ; Mahesh, Devulapally ; Sar, Dinabandhu ; Punniyamurthy, Tharmalingam (2013) Oxidative aromatic C-H functionalization promoted by phenyliodine(III) diacetate to form C-N, C-S, and C-Se bonds Asian Journal of Organic Chemistry, 2 (10). pp. 843-847. ISSN 2193-5807

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ajoc.20...

Related URL: http://dx.doi.org/10.1002/ajoc.201300151

Abstract

Metal-free oxidative syntheses of benzo[d]imidazo[2,1-b]benzo-thiazoles, benzimidazole-2-thiones, N-aryl benzimidazoles, and benzo[d]imidazo[2,1-b]benzoselenozoles are described. C-N, C-S, and C-Se bonds are formed from by aromatic C-H functionalization promoted by phenyliodine(III) diacetate. EDG=electron-withdrawing group; EWG=electron-donating group; HFIP=1,1,1,3,3,3,-hexafluoro-2-propanol; TFA=trifluoroacetic acid.

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