CuO nanoparticles catalyzed C−N, C−O, and C−S cross-coupling reactions: scope and mechanism

Jammi, Suribabu ; Sakthivel, Sekarpandi ; Rout, Laxmidhar ; Mukherjee, Tathagata ; Mandal, Santu ; Mitra, Raja ; Saha, Prasenjit ; Punniyamurthy, Tharmalingam (2009) CuO nanoparticles catalyzed C−N, C−O, and C−S cross-coupling reactions: scope and mechanism Journal of Organic Chemistry, 74 (5). pp. 1971-1976. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo8024253

Related URL: http://dx.doi.org/10.1021/jo8024253

Abstract

CuO nanoparticles have been studied for C−N, C−O, and C−S bond formations via cross-coupling reactions of nitrogen, oxygen, and sulfur nucleophiles with aryl halides. Amides, amines, imidazoles, phenols, alcohols and thiols undergo reactions with aryl iodides in the presence of a base such as KOH, Cs2CO3, and K2CO3 at moderate temperature. The procedure is simple, general, ligand-free, and efficient to afford the cross-coupled products in high yield.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:106327
Deposited On:22 Jun 2017 10:27
Last Modified:22 Jun 2017 10:27

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