Dinadayalane, Tandapani C. ; Priyakumar, U. Deva ; Sastry, G. Narahari (2002) Ring closure synthetic strategies toward buckybowls: benzannulation versus cyclopentannulation Journal of Chemical Soceity, Perkin Transactions 2 (1). pp. 94-101. ISSN 1472-779X
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2002...
Related URL: http://dx.doi.org/10.1039/B108030J
Abstract
Computations were performed on idealized retrosynthetic routes towards two model buckybowl compunds, sumanene (I) and pinakene (II). Two possible paths for sumanene (I) and six for pinakene (II) were analyzed. The computational results unequivocally predict that benzannulation is a significantly easier process compared to cyclopentannulation in the ring closure strategies in both cases. The suitability of the theoretical models for obtaining reliable trends is assessed and generalizations for the synthetic strategies directed towards buckybowls and C60 were made.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 106325 |
| Deposited On: | 28 Jul 2017 09:45 |
| Last Modified: | 28 Jul 2017 09:45 |
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