Cadmium(II)-catalyzed C-N cross-coupling of amines with aryl iodides

Rout, Laxmidhar ; Saha, Prasenjit ; Jammi, Suribabu ; Punniyamurthy, Tharmalingam (2008) Cadmium(II)-catalyzed C-N cross-coupling of amines with aryl iodides Advanced Synthesis & Catalysis, 350 (3). pp. 395-398. ISSN 1615-4150

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...

Related URL: http://dx.doi.org/10.1002/adsc.200700480

Abstract

Cadmium diacetate dihydrate [Cd(OAc)2⋅2 H2O] in combination with ethylene glycol catalyzes efficiently the C-N cross-coupling of amines with aryl iodides by a benzyne mechanism. Alkyl, aryl and heterocyclic amines are compatible with this system affording the aminated products in high to excellent yield.

Item Type:Article
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Deposited On:22 Jun 2017 10:30
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