Punniyamurthy, T. ; Rout, Laxmidhar (2008) Recent advances in copper-catalyzed oxidation of organic compounds Coordination Chemistry Reviews, 252 (1-2). pp. 134-154. ISSN 0010-8545
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.ccr.2007.04.003
Abstract
The copper-catalyzed oxidation of organic compounds has made considerable progress in the recent years. Molecular oxygen, aqueous hydrogen peroxide, tert-butyl hydroperoxide and peroxyesters have been employed as terminal oxidants for this purpose. The use of polymer and solid-supported catalysts, ionic liquids and fluorous biphase systems (FBS) has been demonstrated to facilitate the recyclability of the catalysts. Efforts have been made for the aqueous oxidation processes employing water-soluble copper complexes. Chiral catalysts have been designed and developed for the enantioselective oxidative coupling of 2-naphthols, Baeyer–Villiger oxidation and Kharasch–Sosnovsky reaction with high enantioselectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Oxidation; Organic Compounds; Copper Catalysts; Molecular Oxygen; Hydroperoxide; Peroxyester; Iodosylbenzene |
| ID Code: | 106254 |
| Deposited On: | 22 Jun 2017 10:30 |
| Last Modified: | 22 Jun 2017 10:30 |
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