Theory provides a clue to accomplish the synthesis of sumanene, C21H12, the prototypical C3v-buckybowl

Priyakumar, U. Deva ; Sastry, G. Narahari (2001) Theory provides a clue to accomplish the synthesis of sumanene, C21H12, the prototypical C3v-buckybowl Tetrahedron Letters, 42 (7). pp. 1379-1381. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)02249-8

Abstract

Two possible synthetic routes, namely a triphenylene route and a trindene route for the synthesis of sumanene, C21H12 (2CH2) and trithiasumanene, C18S3H6 (2S) are analyzed in detail. Theoretical calculations unequivocally predict that the synthesis of sumanene may be easily achieved through a trindene route.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Buckybowls; Sumanene; Trindene; Theoretical Calculations; Heterobuckybowls
ID Code:106248
Deposited On:28 Jul 2017 09:44
Last Modified:28 Jul 2017 09:44

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