“Click” synthesis of isomeric compounds for assessing the efficiency of the bifurcated Br⋯NO2 synthon

Ramana, C. V. ; Chatterjee, Soumitra ; Durugkar, Kulbhushan A. ; Gonnade, Rajesh G. (2009) “Click” synthesis of isomeric compounds for assessing the efficiency of the bifurcated Br⋯NO2 synthon CrystEngComm, 11 (1). pp. 143-150. ISSN 1466-8033

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2009...

Related URL: http://dx.doi.org/10.1039/B809985E

Abstract

We report herein the extention of the azide–alkyne “click reaction” to crystal engineering and synthesize a collection of isomeric compounds with modular positioning of Br and NO2 on a tricyclic template and crystal structural analyses of the derived isomers. It is quite remarkable to notice that none of the isomers displayed the bifurcated three-center NO2⋯Br supramolecular synthon in their crystal structures

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