Prasad, K. R. K. ; Joshi, N. N. (1996) An optimised in situ procedure for the oxazaborolidine catalysed enantioselective reduction of prochiral ketones Tetrahedron: Asymmetry, 7 (11). pp. 3147-3152. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0957-4166(96)00416-8
Abstract
A systematic study was conducted to formulate the optimal reaction parameters for the oxazaborolidine catalysed enantioselective reduction. The catalyst derived from diphenyl prolinol was found to be the best amongst several other analogues and a reduction temperature of 45 °C is recommended for high enantioselectivity (92–99% ee) for the reduction of alkyl aryl ketones.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 106043 |
| Deposited On: | 21 Dec 2017 12:03 |
| Last Modified: | 21 Dec 2017 12:03 |
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