Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization

Goriya, Yogesh ; Ramana, Chepuri V. (2013) Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization Chemical Communications, 49 (57). pp. 6376-6378. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2013...

Related URL: http://dx.doi.org/10.1039/C3CC41348A

Abstract

ortho-Bromophenyl sec-alkyl/sec-alkenyl ketones, on reaction with sodium azide in the presence of copper salts, undergo sequential SNAr followed by Smalley cyclization to provide pseudo-indoxyl derivatives. Some of these pseudo-indoxyl derivatives exhibit interesting fluorescent properties and broad Stokes shifts.

Item Type:Article
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ID Code:105998
Deposited On:01 Feb 2018 16:52
Last Modified:01 Feb 2018 16:52

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