Total synthesis of the putative structure of Xylarinol B

More, Atul A. ; Ramana, Chepuri V. (2014) Total synthesis of the putative structure of Xylarinol B Chemistry - An Asian Journal, 9 (6). pp. 1557-1562. ISSN 1861-4728

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/asia.20...

Related URL: http://dx.doi.org/10.1002/asia.201301647

Abstract

The total synthesis of the putative structure of xylarinol B is described and the need to revise its structure is demonstrated. The central benzoxepine skeleton was constructed by employing a cobalt-mediated bimolecular [2+2+2] Reppe–Vollhardt alkyne cycloaddition reaction.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Chiral Pool; Cobalt; Natural Products; Structure Elucidation; Total Synthesis
ID Code:105990
Deposited On:01 Feb 2018 16:52
Last Modified:01 Feb 2018 16:52

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