Total synthesis of naturally occurring cephalosporolides E/F

Kona, Chandrababu Naidu ; Ramana, C.V. (2014) Total synthesis of naturally occurring cephalosporolides E/F Tetrahedron, 70 (23). pp. 3653-3656. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2014.04.026

Abstract

A modular total synthesis of cephalosporolides E/F featuring sequential epoxide–alkyne coupling and subsequent highly regioselective gold catalyzed alkynolcycloisomerization of the resulting alkynetetrol to construct the central spiroketal core has been documented.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Cephalosporolide; Epoxide-Alkyne Coupling; Gold Catalysis; Alkynetetrol; Spiroketalization
ID Code:105932
Deposited On:01 Feb 2018 16:52
Last Modified:01 Feb 2018 16:52

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