Copper catalyzed oxidation of sulfides to sulfoxides with aqueous hydrogen peroxide

Velusamy, Subbarayan ; Kumar, Akkilagunta V. ; Saini, Rakesh ; Punniyamurthy, T. (2005) Copper catalyzed oxidation of sulfides to sulfoxides with aqueous hydrogen peroxide Tetrahedron Letters, 46 (22). pp. 3819-3822. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.03.194

Abstract

Copper(II) complex 1 catalyzes the oxidation of sulfides to sulfoxides with 30% H2O2 in high yields. Addition of a catalytic amount of TEMPO to the reaction mixture enhances the conversion and selectivity. Complex 1 can be recycled without loss of activity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Oxidation; Sulfide; Hydrogen peroxide; CuSalenH4; TEMPO
ID Code:105858
Deposited On:22 Jun 2017 10:37
Last Modified:22 Jun 2017 10:37

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