Pandey, D.S. ; Sahay, A.N. ; Sisodia, Om Singh ; Jha, N.K. ; Sharma, Pankaj ; Klaus, H.E. ; Cabrera, A. (1999) Synthesis, characterization and crystal structure of [(η6-C6Me6)Ru(μ-Cl)3Ru(η6-C6Me6)]PF6 Journal of Organometallic Chemistry, 592 (2). pp. 278-282. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0022-328X(99)00563-X
Abstract
Reaction of [{Ru(η6-C6Me6)Cl2}2] with silver trifluoroacetate in presence of ammonium hexafluorophosphate and organonitriles viz. 4-cyanopyridine, 1,4-piperazine dicarbonitrile or 1,4-dicyanobenzene in methanol gives trichloro bridged complex [(η6-C6Me6) Ru(μ-Cl)3Ru(η6-C6Me6)]PF6. The complex has been characterized by various physico-chemical techniques (Elemental analyses, IR,UV–vis, 1H-, 13C-, 31P-NMR and FAB mass spectroscopy) and single crystal X-ray diffraction studies. [Crystal data: monoclinic, space group P21c, a=10.7604(9), b=24.897(2), c=10.8833(11) Å, β=100.990(7)°.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ruthenium Complexes; Trichloro Bridged Hexa Methylbenzene Complex |
| ID Code: | 105712 |
| Deposited On: | 20 Apr 2017 06:19 |
| Last Modified: | 20 Apr 2017 06:19 |
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