Pawar, Amit B. ; Prasad, Kavirayani R. (2012) Formal total synthesis of palmerolide A Chemistry - A European Journal, 18 (47). pp. 15202-15206. ISSN 0947-6539
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.201202324
Abstract
A formal total synthesis of the 20-membered marine macrolide, palmerolide A from chiral pool tartaric acid is described. Elaboration of a γ-hydroxy amide, which is derived from the desymmetrization of tartaric acid amide, and Boord olefination are the pivotal reactions employed for the synthesis of the chiral building blocks, and Stille coupling and ring-closing metathesis (RCM) are used to assemble the macrolactone.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Macrolactone; Metathesis; Natural Products; Olefination; Palmerolide A; Total Synthesis |
| ID Code: | 105691 |
| Deposited On: | 21 Dec 2017 12:01 |
| Last Modified: | 21 Dec 2017 12:01 |
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