Jemmis, Eluvathingal D. ; Subramanian, G. ; Narahari Sastry, G. ; Mehta, G. ; Shirsat, Rajendra N. ; Gadre, Shridhar R. (1996) Molecular electrostatic potential topographical studies on the structural motifs of C60 Journal of the Chemical Society. Perkin transactions 2, 2 . pp. 2343-2346. ISSN 0300-9580
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Official URL: http://www.rsc.org/Publishing/Journals/P2/article....
Related URL: http://dx.doi.org/10.1039/P29960002343
Abstract
Molecular electrostatic potential topographical studies on the structural motifs of C60 reveal unusual features. Ethylene, [5]radialene and corannulene are predicted to be structural motifs present in C60. However, benzene does not fit into this framework. The double bonds in all the above molecules are activated upon pyramidalization at the carbon centre, the extent depending on the anisotropic environment of the conjugated carbon. The peripheral double bonds in corannulene are predicted to be more susceptible to electrophilic attack in comparison to the exocyclic double bonds of the five-membered ring.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 10569 |
| Deposited On: | 04 Nov 2010 05:06 |
| Last Modified: | 31 May 2011 10:24 |
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