Retrieval and validation of Chlorophyll-a concentrations in the coastal waters off Yanam and Kakinada (Godavari) basin along east coast of India

Abstract

In this study chlorophyll measurements were made during March 2012 in the estuarine waters of Off Kakinada and Yanam coast, Bay of Bengal onboard a coastal vessel. In-situ water samples and optical data was collected at 21 stations (surface to 150 m depth) using Underwater radiometer (Hyperpro-II). In-vivo chlorophyll profiles were collected using wet labs fluorometer integrated with underwater Hyperspectral radiometer. Chlorophyll-a concentrations were estimated using HPLC by collecting the water samples at each sampling location. And also chlorophyll-a concentrations were retrieved from the OCM-2 data of OCEANSAT-2 satellite, processed using SeaDAS v.6.2 with the available global ocean colour algorithms namely, OC2 and OC₄V₄. A total of 33 samples used covering all the stations for chlorophyll-a estimation, and surface water samples of all the stations only being used for direct comparison among chlorophyll concentrations of HPLC, in-situ (fluorometrically integrated to Hyperpro-II) and retrieved from OCM-2. A good correlation found between the Fluorometer derived and HPLC measured chlorophyll-a concentration with an R² value of 0.78. The relation between Chlorophyll-a concentration measured from HPLC and retrieved from OCM-2 (OC2 and OC₄V₄ algorithms) using SeaDASv.6.2 for 10 samples has been compared for validation and obtained an R² value of 0.6. Also comparisons done with the in-situ measured (fluorometer) Chlorophyll-a concentration with OCM-2 chlorophyll data (OC4-V4 and OC2 algorithms) and validation with 10 concurrent in-situ surface measurements showed a significant overestimation by OCM-2 at low chlorophyll-a concentrations and underestimation at high chlorophyll-a concentrations.