Chiral Mn-salen catalyzed enantiotopic selective C−H oxidation of meso-pyrrolidine derivatives

Punniyamurthy, T. ; Miyafuji, Akio ; Katsuki, Tsutomu (1998) Chiral Mn-salen catalyzed enantiotopic selective C−H oxidation of meso-pyrrolidine derivatives Tetrahedron Letters, 39 (45). pp. 8295-8298. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(98)80001-4

Abstract

Asymmetric desymmetrization of meso-pyrrolidine derivatives was first effected by enantioselective oxidation of the C−H bond α to the nitrogen atom using Mn-salen complex 1b as a catalyst.

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ID Code:105639
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