Enantiospecific total synthesis of macrolactone Sch 725674

Bali, Amit K. ; Sunnam, Sunil K. ; Prasad, Kavirayani R. (2014) Enantiospecific total synthesis of macrolactone Sch 725674 Organic Letters, 16 (15). pp. 4001-4003. ISSN 1523-7060

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/ol5018678

Related URL: http://dx.doi.org/10.1021/ol5018678

Abstract

The enantiospecific total synthesis of 14-membered macrolactone Sch 725674 was accomplished from tartaric acid. Key reactions in the synthesis include the Ley’s dithiaketalization of an alkynone derived from the bis-Weinreb amide of tartaric acid, Boord olefination, and ring-closing metathesis of an acrylate ester.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:105629
Deposited On:21 Dec 2017 12:02
Last Modified:21 Dec 2017 12:02

Repository Staff Only: item control page