Singh, Sanjay K. ; Chandra, Manish ; Pandey, Daya S. (2004) Ru(II) complexes imparting N2O2 donor bis chelating ligand N,N′-bis(salicylidine)-hydrazine in unusual coordination mode Journal of Organometallic Chemistry, 689 (12). pp. 2073-2079. ISSN 0022-328X
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2004.03.031
Abstract
The synthesis and characterization of binuclear ruthenium complexes [{(η6-C6H6)Ru}2(μ-bsh)2](1), [{(η6-C10H14)Ru}2(μ-bsh)2] (2), [{(η6-C6Me6)Ru}2(μ-bsh)2] (3), and rhodium complex [{(η5-C5Me5)RhCl}2(μ-bsh)] (4) (bsh=N,N′-bis(salicylidine)-hydrazine dianion) are reported. The complexes have been fully characterized by analytical and spectral techniques and unusual coordination mode of the ligand H2bsh has been confirmed by single crystal X-ray analysis of the complex 2. Structural data revealed extensive inter- and intra-molecular C–H⋯O and C–H⋯π interactions and involvement of methyl and isopropyl hydrogen from the p-cymene in hydrogen bonding.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ruthenium; Arene; N,N′-bis(salicylidine)-hydrazine; X-ray; Interaction |
| ID Code: | 105618 |
| Deposited On: | 20 Apr 2017 07:02 |
| Last Modified: | 20 Apr 2017 07:03 |
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