Trivedi, Manoj ; Pandey, Daya Shankar ; Zou, Ru-Qiang ; Xu, Qiang (2008) Novel Rh(III) pentamethylcyclopentadienyl and Ru(II) cyclopentadienyl complexes containing 1,3,5-triazine-2,4,6-trithiol in trinucleating mode Inorganic Chemistry Communications, 11 (5). pp. 526-530. ISSN 1387-7003
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2007.12.039
Abstract
Two homo-trinuclear complexes [{(η5-C5Me5)RhCl}3(μ3-L)] (1) and [{(η5-C5H5)Ru(PPh3)}3(μ3-L)] (2) (H3L=2,4,6-trimercapto-1,3,5-triazine) are reported. Both the complexes have been fully characterized by elemental analyses, FAB-MS, IR, NMR, electronic and emission spectral techniques. Molecular structure of 1 has been authenticated by single crystal X-ray diffraction analyses. Complex 1 revealed the strong intra- and inter-molecular C–H⋯X (X= Cl, π) and π–π stacking interactions, which play important roles to stabilize crystal space packing. Furthermore, the π–π interactions in 1 lead to a double-helical motif.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Rhodium–Cp∗; Ruthenium–Cp; Trithiocyanuric Acid; X-ray; Emission; Weak Interactions |
| ID Code: | 105548 |
| Deposited On: | 20 Apr 2017 10:34 |
| Last Modified: | 20 Apr 2017 10:34 |
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