Zhong, Rui-Qin ; Zou, Ru-Qiang ; Pandey, Daya S. ; Kiyobayashi, Tetsu ; Xu, Qiang (2008) A novel 3D microporous metal-organic framework of cadmium(II) oxalate with diamondoid network Inorganic Chemistry Communications, 11 (9). pp. 951-953. ISSN 1387-7003
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2008.05.010
Abstract
A three-dimensional (3D) metal-organic framework of cadmium(II) oxalate, [Cd(C2O4)2(H2O)](H2O)(H3O)2C2H5OH) 1, has been created by decomposition of pyridine-2,4,6-tricarboxylic acid under solvothermal reaction condition. Single crystal X-ray diffraction analysis shows that complex 1 self-assembles into a 3D noninterpenetrated diamondoid network with open channels accommodating guest ethanol and water molecules. The thermostability and nitrogen adsorptive property of 1 were investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Solvothermal Synthesis; Oxalate; Diamondoid Network; Thermostability; Adsorptive Property |
| ID Code: | 105529 |
| Deposited On: | 20 Apr 2017 10:39 |
| Last Modified: | 20 Apr 2017 10:39 |
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