Mehta, Goverdhan ; Khan, Faiz Ahmed ; Gadre, Shridhar R. ; Shirsat, Rajendra N. ; Ganguly, Bishwajit ; Chandrasekhar, Jayaraman (1994) Electrostatic vs. Orbital control of facial selectivities in p systems: experimental and theoretical study of electrophilic additions to 7-isopropylidenenorbornanes Angewandte Chemie International Edition, 33 (13). pp. 1390-1392. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...
Related URL: http://dx.doi.org/10.1002/anie.199413901
Abstract
Predominantly orbital effects determine the pre ferred syn attack of electrophiles on the norbornane derivative 1 bearing an electron-withdrawing endo substituent. This finding is the result of topological analyses of the electrostatic potentials from ab initio calculations and a comparison of the energies of the transition states calculated with semiempirical methods. R = CN, COOCH3.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 10548 |
| Deposited On: | 04 Nov 2010 05:10 |
| Last Modified: | 16 Jul 2012 07:54 |
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