Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole

Sharma, Ritambhara ; Lee, Way-Zen ; Ravikanth, Mangalampalli (2015) Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole RSC Advances, 5 (124). pp. 102765-102771. ISSN 2046-2069

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2015...

Related URL: http://dx.doi.org/10.1039/C5RA21947G

Abstract

The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp3 meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp3 meso carbon.

Item Type:Article
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ID Code:104941
Deposited On:01 Dec 2017 10:55
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