A stable seven-membered heterocycle, containing B, C, N, O and P atoms, inside a smaragdyrin macrocycle

Kalita, Hemanta ; Lee, Way-Zen ; Theophall, Gregory G. ; Lakshmi, K. V. ; Ravikanth, M. (2015) A stable seven-membered heterocycle, containing B, C, N, O and P atoms, inside a smaragdyrin macrocycle Chemistry - A European Journal, 21 (32). pp. 11315-11319. ISSN 0947-6539

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...

Related URL: http://dx.doi.org/10.1002/chem.201501889

Abstract

Unprecedented examples of smaragdyrin macrocycles containing seven membered heterocyclic rings were synthesized under simple reaction conditions in high yields. The heterocycle formed inside smaragdyrin macrocycle is rare example of heterocycle containing five different atoms, such as B, C, N, O and P atoms. The mixed BIII and PV complexes of smaragdyrin macrocycles showed new structural, spectral and electrochemical properties.

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ID Code:104934
Deposited On:30 Nov 2017 12:18
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