Efficient metathesis route to the B-ring of eleutherobin and other medium-sized cyclic ethers

Kaliappan, Krishna P. ; Kumar, Nirmal (2005) Efficient metathesis route to the B-ring of eleutherobin and other medium-sized cyclic ethers Tetrahedron, 61 (31). pp. 7461-7469. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2005.05.045

Abstract

A short and efficient RCM route is reported for the synthesis of the B-ring of eleutherobin and other medium-sized cyclic ethers from readily available 1,2,5,6-diisopropylidene-D-glucose. This strategy is successfully extended to the synthesis of a few bicyclic ethers, which may find applications in the synthesis of novel bicyclic nucleosides.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Eleutherobin; Cyclic Ethers; Ring Closing Metathesis; Grubbs' Catalyst; Bicyclic Nucleosides
ID Code:104891
Deposited On:23 May 2017 05:42
Last Modified:23 May 2017 05:42

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