Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides

Choudhary, V. R. ; Dumbre, D. K. ; Uphade, B. S. ; Narkhede, V. S. (2004) Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides Journal of Molecular Catalysis A: Chemical, 215 (1-2). pp. 129-135. ISSN 1381-1169

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13811...

Related URL: http://dx.doi.org/10.1016/j.molcata.2004.01.009

Abstract

Performance of Mn-Al, Co-Al, Ni-Al, Zn-Al, Mg-Fe, Mn-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-Cr, Ni-Cr, Cu-Cr, and Zn-Cr layered double hydroxides (LDH) and/or mixed hydroxides (HD) solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using TBHP as an oxidizing agent in the absence of any solvent. The Mn, Cu, and Co containing LDH solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation of benzyl alcohol to benzaldehyde.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Oxidation of Benzyl Alcohol to Benzaldehyde; Transition Metal Containing Hydrotalcite-like Catalysts; Solvent-free Oxidation of Benzyl Alcoholol
ID Code:10466
Deposited On:03 Nov 2010 11:50
Last Modified:28 May 2011 11:15

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