Novel and rapid synthetic routes to A3B and AB3-type 21-thiaporphyrins and their use in the construction of unsymmetrical covalent and non-covalent porphyrin arrays

Gupta, Iti ; Agarwal, Neeraj ; Ravikanth, Mangalampalli (2004) Novel and rapid synthetic routes to A3B and AB3-type 21-thiaporphyrins and their use in the construction of unsymmetrical covalent and non-covalent porphyrin arrays European Journal of Organic Chemistry, 2004 (8). pp. 1693-1697. ISSN 1434-193X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...

Related URL: http://dx.doi.org/10.1002/ejoc.200300764

Abstract

Novel and very simple methods were developed for the synthesis of 21-thiaporphyrins having both one functional group (A3B) and three functional groups (AB3). These A3B- and AB3-type 21-thiaporphyrin building blocks were used to synthesize both covalently and non-covalently linked unsymmetrical porphyrin arrays containing N3S and N4 porphyrin cores.

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