Synthesis of single strapped 21-thia tetraphenylporphyrin systems

Boobalan, P. ; Gupta, Iti ; Ravikanth, M. (2002) Synthesis of single strapped 21-thia tetraphenylporphyrin systems Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 41A (9). 1860--1863. ISSN 0376-4710

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Official URL: http://nopr.niscair.res.in/handle/123456789/18405

Abstract

Synthesis and characterization of two single strapped 21-thia tetraphenylporphyrin have been reported. The two adjacent phenyls that are present at the meso position of 21-thia tetraphenylporphyrin are linked by either rigid aromatic group or flexible alkyl chain. Absorption and fluorescence studies indicated that the rigid aromatic group induced more nonplanarity in the porphyrin ring than flexible alkyl chain.

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ID Code:104520
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