Sorption capacity and diffusion of pure liquids in ZSM-5 type zeolites

Choudhary, V. R. ; Singh, A. P. (1986) Sorption capacity and diffusion of pure liquids in ZSM-5 type zeolites Zeolites, 6 (3). pp. 206-208. ISSN 0144-2449

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/014424...

Related URL: http://dx.doi.org/10.1016/0144-2449(86)90049-7

Abstract

Simple and inexpensive methods described for measuring precisely the crystal density, the inter- and intracrystalline pore volumes and the sorption capacity of the ZSM-5 zeolite and also for studying the single component diffusion of very slow diffusing liquids in the zeolite. The sorption capacity of H-ZSM-5 (Si/Al = 38) for the different sorbates was found to be in the following order: methanol >> n-hexane ≈ benzene > p-xylene >m-xylene ≈ o-xylene > mesitylene. The values of diffusion coefficients for o-xylene, m-xylene and mesitylene at 303 K were found to be 24.0 × 10-15, 16.1 × 10-15 and 0.9 × 10-15 cm2 s-1, respectively.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:ZSM-5; Sorption Capacity; Diffusion; Methods for Micro and Macroporosity
ID Code:10424
Deposited On:03 Nov 2010 16:32
Last Modified:30 May 2011 04:55

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