Dey, Santu ; Datta, Dhrubajyoti ; Pathak, Tanmaya (2011) A metal-free, aqueous and general route to 1,5-disubstituted-1,2,3-triazoles: ‘reversed regioisomeric’ 1,3-dipolar cycloaddition of azides and vinyl sulfones Synlett (17). pp. 2521-2524. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/products/ejournals/...
Related URL: http://dx.doi.org/10.1055/s-0030-1260306
Abstract
A metal-free, vinyl sulfone-based synthesis of 1,5-disubstituted-1,2,3-triazoles is reported for the first time. These triazoles are easily formed in a regioselective fashion by heating under reflux a mixture of a substituted vinyl sulfone and an organic azide ‘on water’. This powerful and practical route has the potential to be exploited for the synthesis of complex 1,5-disubstituted-1,2,3-triazoles.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | Triazoles; On Water; Vinyl Sulfone; Organic Azide; Click Chemistry |
| ID Code: | 103923 |
| Deposited On: | 17 Mar 2017 11:56 |
| Last Modified: | 17 Mar 2017 11:56 |
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