Kumar, Ashish ; Dubey, Mrigendra ; Kumar, Amit ; Pandey, Daya Shankar (2014) A saponification-triggered gelation of ester-based Zn(II) complex through conformational transformations Chemical Communications, 50 (70). pp. 10086-10089. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2014...
Related URL: http://dx.doi.org/10.1039/C4CC03537B
Abstract
Novel saponification-triggered gelation in an ester-based bis-salen Zn(II) complex (1) is described. Strategic structural modifications induced by NaOH in 1 tune the dipolar-/π-interactions leading to J-aggregation and the creation of an inorganic gel material (IGM), which has been established by photophysical, DFT and rheological studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 103686 |
| Deposited On: | 23 Apr 2017 16:00 |
| Last Modified: | 23 Apr 2017 16:00 |
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