Anion directed conformational diversities of an arene based hexa-amide receptor and recognition of the [F2(H4O)6]4− cluster

Chakraborty, Sourav ; Dutta, Ranjan ; Wong, Bryan M. ; Ghosh, Pradyut (2014) Anion directed conformational diversities of an arene based hexa-amide receptor and recognition of the [F2(H4O)6]4− cluster RSC Advances, 4 (107). pp. 62689-62693. ISSN 2046-2069

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2014...

Related URL: http://dx.doi.org/10.1039/C4RA10795K

Abstract

A benzene platform based new hexa-amide receptor (L) has shown conformational diversities via isolation of aaabbb (A), aabaab (B) and aaaaaa (C) conformers upon recognition of acetate, nitrate and hydrated-fluoride [F2(H4O)2]4− respectively in the solid state. Solution and DFT calculation studies show fluoride binding selectivity of L.

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