Tris(2-aminoethyl)amine based tripodal urea receptors for oxalate: encapsulation of staggered vs. planar conformers

Bose, Purnandhu ; Dutta, Ranjan ; Ghosh, Pradyut (2013) Tris(2-aminoethyl)amine based tripodal urea receptors for oxalate: encapsulation of staggered vs. planar conformers Organic & Biomolecular Chemistry, 11 (28). pp. 4581-4584. ISSN 1477-0520

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2013...

Related URL: http://dx.doi.org/10.1039/C3OB41071D

Abstract

Simple tris(2-aminoethyl)amine (TREN) based tripodal urea receptors are investigated for the encapsulation of divalent oxalate (C2O42−) in a semi-aqueous medium. A single crystal X-ray diffraction study shows that the receptor with 3-cyanophenyl functionality captures a staggered conformer whereas the 3-fluorophenyl functionalized receptor encapsulates a less stable planar conformer.

Item Type:Article
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ID Code:102565
Deposited On:23 Jan 2017 06:45
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