Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing P(OH)2(OMe) ligand

Nagaraja, C. M. ; Nethaji, Munirathinam ; Jagirdar, Balaji R. (2004) Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing P(OH)2(OMe) ligand Inorganic Chemistry Communications, 7 (5). pp. 654-656. ISSN 1387-7003

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.inoche.2004.03.008

Abstract

A stable, coordinatively unsaturated, 16-electron ruthenium complex bearing P(OH)2(OMe) has been synthesized and characterized. It reacts with H2 resulting in a highly acidic dihydrogen complex.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Acidity; Dihydrogen Complex; Hydride Complex; Diphosphine; Phosphite; Ruthenium
ID Code:102272
Deposited On:12 Feb 2018 12:19
Last Modified:12 Feb 2018 12:19

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