A hybrid water–chloride structure with discrete undecameric water moieties self-assembled in a heptaprotonated octaamino cryptand

Lakshminarayanan, P. S. ; Suresh, Eringathodi ; Ghosh, Pradyut (2006) A hybrid water–chloride structure with discrete undecameric water moieties self-assembled in a heptaprotonated octaamino cryptand Angewandte Chemie International Edition, 45 (23). pp. 3807-3811. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200600254

Abstract

Odd water clusters: An unprecedented propeller-shaped undecameric water motif is stabilized within the lattice of the heptahydrochloride of a homoditopic octaamino cryptand with C3 symmetry. The discrete water clusters are oriented symmetrically around the cryptand moiety and interact with encapsulated chloride inside the cavity (see structure; Cl green, O red, N blue).

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