The existence of ferroelectric-antiferroelectric fluctuations in Rb1-x(NH4)xH2PO4

Babu, Y. ; Sastry, M. D. ; Dasannacharya, B. A. (1994) The existence of ferroelectric-antiferroelectric fluctuations in Rb1-x(NH4)xH2PO4 Journal of Physics: Condensed Matter, 6 (15). pp. 2975-2976. ISSN 0953-8984

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Official URL: http://iopscience.iop.org/0953-8984/6/15/021

Related URL: http://dx.doi.org/10.1088/0953-8984/6/15/021

Abstract

By taking 75As hyperfine coupling constants for AsO44- in hydrogen bonded crystals of RbH2PO4 and (NH4)H2PO4 as fingerprints of ferroelectric (FE) and antiferroelectric (AFE) phases respectively, it is shown that the variation of the coupling constant as a weighted average of Rb+ and NH4+ concentrations in Rb1-x(NH4)xH2PO4 clearly proves the existence of FE and AFE fluctuations in the mixed crystal.

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