Katz, Benjamin ; Park, Jeunghee ; Satyapal, Sunita ; Tasaki, Shintaro ; Chattopadhyay, Arun ; Yi, Whikun ; Bersohn, Richard (1991) Exchange reactions of hydrogen atoms with SiD4: an inversion mechanism? Faraday Discussions, 91 . pp. 73-78. ISSN 0301-7249
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1991...
Related URL: http://dx.doi.org/10.1039/DC9919100073
Abstract
The reaction H + SiD4→ D + SiH3D is found to have a much lower threshold than the corresponding exchange reaction of H with CD4. The D atom carries away most of the initial translational energy of the H atom. When the H-atom velocity distribution is anisotropic, the D-atom velocity distribution is anisotropic in the same sense. The exchange cross-sections for the reaction H + SiH3D are about one half of those for SiD4. All this evidence leads to the conclusion that the mechanism of the exchange is an inversion.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 101478 |
| Deposited On: | 15 Dec 2016 12:15 |
| Last Modified: | 15 Dec 2016 12:15 |
Repository Staff Only: item control page
