Inter-ring exchange interactions in the excited electronic state of bridged diaryl compounds: exciton splitting in 9,10-dihydroanthracene and dibenzosuberane

Zgierski, Marek Z. ; Chakraborty, Tapas ; Lim, E. C. (1993) Inter-ring exchange interactions in the excited electronic state of bridged diaryl compounds: exciton splitting in 9,10-dihydroanthracene and dibenzosuberane The Journal of Chemical Physics, 98 (12). Article ID 9340. ISSN 0021-9606

Full text not available from this repository.

Official URL: http://scitation.aip.org/content/aip/journal/jcp/9...

Related URL: http://dx.doi.org/10.1063/1.464413

Abstract

The fluorescence excitation spectra of jet‐cooled 9,10‐dihydroanthracene and dibenzosuberane, in the region of their lowest‐energy absorption band, exhibit two close‐lying electronic origins that can be identified as the two exciton components of the lowest‐energy benzene transition. The measured band positions and intensities of the two exciton components are in good agreement with the results of CNDO/S+CIS calculations based on the optimized QCFF/PI+CIS ground‐state geometry.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
ID Code:100601
Deposited On:06 Dec 2016 11:55
Last Modified:06 Dec 2016 11:55

Repository Staff Only: item control page