Synthesis and nonlinear optical properties of some donor-acceptor oxadiazoles

Mashraqui, Sabir H. ; Kenny, Rajesh S. ; Ghadigaonkar, Shailesh G. ; Krishnan, Anu ; Bhattacharya, Mily ; Das, Puspendu K. (2004) Synthesis and nonlinear optical properties of some donor-acceptor oxadiazoles Optical Materials, 27 (2). pp. 257-260. ISSN 0925-3467

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09253...

Related URL: http://dx.doi.org/10.1016/j.optmat.2004.04.006

Abstract

Heterocyclic 1,3,4-oxadiazole moiety has been used as a new p-conjugation relay to prepare a number of donor-acceptor molecules carrying a p-electron-rich aromatic ring as a donor and either a p-nitrophenyl or a pyridine/pyridinium ring as an acceptor. Several of these oxadiazoles display significant second-order molecular nonlinearity, β (14-124 × 10-30 esu) and provide the basis for future design of efficient nonlinear optical materials having the oxadiazole core.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Nonlinear Optics; first Hyperpolarizability; Donor-acceptor Oxadiazoles; Synthesis; UV-visible; Hyper-rayleigh Scattering Technique; Thermal Decomposition
ID Code:10056
Deposited On:02 Nov 2010 09:57
Last Modified:30 May 2011 10:18

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