I production from n-alkyl iodides at 222 nm

Uma, S. ; Das, Puspendu Kumar (1995) I production from n-alkyl iodides at 222 nm Chemical Physics Letters, 241 (4). pp. 335-338. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(95)00661-M


The dynamics of I(2P½) production in a series of n-alkyl iodides at 222 run have been investigated. Data are analyzed using a simple classical impulsive model. At this excitation wavelength, 1 (2P3/2) originates from a curve-crossing between the 3Q0 and 1Q1 surfaces and the probability of crossing for all the iodides has been derived. Since the I quantum yield is found to decrease, the probability of crossing increases as a function of the alkyl radical size, which is also consistent with the classical model.

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ID Code:10044
Deposited On:02 Nov 2010 10:03
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