Palladium catalyzed Csp2–H activation for direct aryl hydroxylation: the unprecedented role of 1,4-dioxane as a source of hydroxyl radicals

Seth, Kapileswar ; Nautiyal, Manesh ; Purohit, Priyank ; Parikh, Naisargee ; Chakraborti, Asit K. (2015) Palladium catalyzed Csp2–H activation for direct aryl hydroxylation: the unprecedented role of 1,4-dioxane as a source of hydroxyl radicals Chemical Communications, 51 (1). pp. 191-194. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2015...

Related URL: http://dx.doi.org/10.1039/C4CC06864E

Abstract

A novel strategy for direct aryl hydroxylation via Pd-catalysed Csp2–H activation through an unprecedented hydroxyl radical transfer from 1,4-dioxane, used as a solvent, is reported with bio relevant and sterically hindered heterocycles and various acyclic functionalities as versatile directing groups.

Item Type:Article
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ID Code:100249
Deposited On:20 Jan 2017 09:45
Last Modified:20 Jan 2017 09:45

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