The palladium and copper contrast: a twist to products of different chemotypes and altered mechanistic pathways

Seth, Kapileswar ; Roy, Sudipta Raha ; Kumar, Asim ; Chakraborti, Asit K. (2016) The palladium and copper contrast: a twist to products of different chemotypes and altered mechanistic pathways Catalysis Science & Technology, 6 (9). pp. 2892-2896. ISSN 2044-4753

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016...

Related URL: http://dx.doi.org/10.1039/C6CY00415F

Abstract

A novel contrast in palladium and copper catalysis is revealed to form products of different chemotypes resulting in a phenazine to azoarene twist through an altered mechanistic pathway (from non-radical C–H activation mode of C–N coupling to radical N–N coupling) during the oxidative self-coupling of anilines catalysed by Pd–Ag and Cu–Ag nanoclusters.

Item Type:Article
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ID Code:100235
Deposited On:12 Feb 2018 12:56
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