Coupling dirhodium units through terpyridine bridges: synthesis and structure of a novel molecular rectangle

Bera, Jitendra K. ; Campos-Fernández, Cristian Saul ; Rodolphe, Clérac ; Dunbar, Kim R. (2002) Coupling dirhodium units through terpyridine bridges: synthesis and structure of a novel molecular rectangle Chemical Communications, 2002 (21). pp. 2536-2537. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2002...

Related URL: http://dx.doi.org/10.1039/B208164B

Abstract

The cation [Rh2(μ-O2CMe)2(MeCN)6]2+ reacts with the bis-terpyridine ligand 2,3,5,6-tetra-2-pyridylpyrazine (tppz) to yield the reduced compound [Rh4(μ-O2CMe)2(tppz)2(MeOH)4]4+ whose structure is that of molecular rectangle with edges defined by short Rh–Rh and long Rh–tppz–Rh units.

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