Heterometallic molecular squares and polymers based on self-assembly reactions of multiply bonded dirhenium complexes

Bera, Jitendra K. ; Bacsa, John ; Smucker, Bradley W. ; Dunbar, Kim R. (2004) Heterometallic molecular squares and polymers based on self-assembly reactions of multiply bonded dirhenium complexes European Journal of Inorganic Chemistry, 2004 (2). pp. 368-375. ISSN 1434-1948

Full text not available from this repository.

Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejic.20...

Related URL: http://dx.doi.org/10.1002/ejic.200300268

Abstract

Self-assembly reactions of the triply-bonded dirhenium complex cis-[Re2Cl2(dppm)2(O2CC5H4N-4)2] with cis-protected PtII and ZnII precursors have produced heterometallic squares. Analogous reactions with Ag(O3SCF3), cis-[Re2Cl4(O2CCH3)2(H2O)2] and [Rh2(O2CCH3)4] have yielded mixed-metal polymeric structures. These results demonstrate that the isonicotinate ligand is useful for accessing heterometallic structures involving metal−metal bonded complexes.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
ID Code:100209
Deposited On:27 Nov 2016 13:23
Last Modified:27 Nov 2016 13:23

Repository Staff Only: item control page